Further players will be announced to join ex-Barcelona duo Ronaldinho and Puyol, former Manchester United and England midfielder Scholes and former France and Arsenal player Pires. Ronaldinho, Pires and Puyol are all World Cup winners.
The Kuwaiti all-star team will be selected via a public vote, which started on Tuesday. Voting closes on December 7, with the team to be coached by Mohammed Ibrahim to be announced the following day.
Iconic Italian referee Pierluigi Collina will officiate at the match.
The Football Champions Tour helped to organise last month’s Match For Children at Old Trafford, which was held to raise money for David Beckham’s UNICEF fund – the 7 Fund. Scholes, Ronaldinho and Pires all turned out in Manchester.